QuNeW is a comprehensive three-day workshop that offers an excellent opportunity for researchers, academics, and industry professionals to come together and explore the latest advances in quantum networks. The event will feature inspiring invited talks from world-leading researchers, complemented by engaging contributed talks and poster sessions. QuNeW is dedicated to providing balanced coverage across the many sub-fields of quantum networking. This workshop serves as a unique platform to exchange ideas, foster collaborations, share knowledge, and drive meaningful progress for all participants involved in the field. QuNeW 2025 is proudly organized by QuTech at TU Delft.